Growth of Silicon- Germanium Alloy Layers

  • C. K. Maiti Indian Institute of Technology Kharagpur, Kharagpur
  • L. K. Bera Indian Institute of Technology Kharagpur, Kharagpur
  • S. Maikap Indian Institute of Technology Kharagpur, Kharagpur
  • S. K. Ray Indian Institute of Technology Kharagpur, Kharagpur
  • N. B. Chakrabarti Indian Institute of Technology Kharagpur, Kharagpur
  • R. Kesavan Solid State Physics Laboratory, Delhi
  • V. Kumar Solid State Physics Laboratory, Delhi
Keywords: Heteroepitaxy techniques, Binary alloys, Gas source molecular beam epitaxy, Heteroepitaxial film deposition, SiGe buffer layers, Hydrogenated amorphous SiGe

Abstract

Heteroepitaxy techniques for the growth of group IV binary alloys, in particular, SiGe, SiC, GeC and SiSn films are reviewed. Deposition of heteroepitaxial films using various reactors like molecular beam epitaxy, gas source molecular beam epitaxy, and different chemical vapour deposition techniques are compared. Issues related to heteroepitaxial film deposition, such as critical layer thickness are examined. Growth of strained silicon on relaxed SiGe buffer layers, poly-SiGe film and hydrogenated amorphous SiGe (a-SiGe:H) film is also reviewed

Author Biographies

C. K. Maiti, Indian Institute of Technology Kharagpur, Kharagpur
Indian Institute of Technology, Kharagpur
L. K. Bera, Indian Institute of Technology Kharagpur, Kharagpur
Indian Institute of Technology Kharagpur, Kharagpur
S. Maikap, Indian Institute of Technology Kharagpur, Kharagpur
Indian Institute of Technology Kharagpur, Kharagpur
S. K. Ray, Indian Institute of Technology Kharagpur, Kharagpur
Indian Institute of Technology Kharagpur, Kharagpur
N. B. Chakrabarti, Indian Institute of Technology Kharagpur, Kharagpur
Indian Institute of Technology, Kharagpur
R. Kesavan, Solid State Physics Laboratory, Delhi

Solid State Physics Laboratory, Delhi

V. Kumar, Solid State Physics Laboratory, Delhi

Solid State Physics Laboratory, Dehli

References

Meyersbn, B.S. UHV/CVD growth of Si and Si1Ge Alloys: Chemistry, physics, and device applications. Proceedings IEEE, 11992, 80,

Bean, J .C. Silicon-babed semiconductor heterostructures: Column I'r bandgap engineering. Proceedings IEEE, 1992, 80, 571-87.

Jain, S.C.1 Germanium-silicon strained layers and heterostructures. Academic Press Inc., NewYork,1994.

Kasper, E. (Ed). Properties of strained and relaxed silicon germanium. INSPEC, Institute of Electrical Engineers, London, 1995.

Konig, U.& Daembkes, H. SiGe HBTs and HFETs. Solid-State Electronics, 1995, 38, 1595-602.

People, R. Physics and applications of Gex Si1-x/Si strained layer heterostructures. IEEE J. Quantum Elec.,' 1986, QE-22, 1696-710.

Nayak, D.K. & Chun, s.K. Low field mobility of strained Si on (loo) Si1--xGex substrate. Appl. Phys. Lett., 1994, 64, 2514-516.

Schaffler, F. High-mobility Si and Ge structures. Semicond. Sci. Technol., 1997, 12, 1515-549.

Maiti, C.K.; Bera, L.K. & Chattopadhyay, S Strained-Si heterostructure field effect transistors Semicond. Sci. Technol., 1998, 13, 1225-246,

Kasper, E. & Falco, C.M. Molecular beam epitaxy of silicon, silicon alloys, and metals. In Advanced silicon and semiconducting siliconalloy- based materials and devices, edited by J. F. A. Nijs. Institute of Physics Publishing,

.Bristol, 1995. pp. 103-40.

Caymax, M.R. & Leong, W.Y. Low thermal budget chemical vapor deposition techniques for Si and SiGe. In Advanced silicon and semiconducting silicon-alloy-based materials and

devices, edited by J.F .A. Nijs. Institute of Physics Publishing, Bristol, 1995. pp.141-83.

Frank, F.C. & Van der Merwe, J.H. Onedimehsionaldislocations, Part II. Misfitting monolayers and oriented overgrowth. Proc. R. Soc., A 1949, 198, 216-25.

Matthews, J.W. & Blakeslee, A.E. Defects in epitaxial multilayers, Part-I. Misfit dislocations. J. Cryst. Growth, 1974, 27, 118-25.

Matthews, J. W. & Blakeslee, A.E. Defects in epitaxial multilayers, Part-II. Dislocation pile upS, threading dislocations, . slip lines and cracks. J. Crys. Growth ,1975, 29, 273-80.

Matthews, J,W. & Blakeslee, A.E. Defects. in epitaxial multilayer, Part-lll. Preparation of almost perfect multilayers. J. crays. Growth, 1976,32,265-73.

People, R. & Bean J.C. Calculation of critical layer thickness versus lattice mismatch for GeXSi1-X/ Si strained layer heterostructures. Appl. Phys. Lett., 1985, 47, 322-24.

Van der Merwe, J .H. Crystal interfAces, Part II. Finite overgrowths. J. Appl. Phys., 1963, 34, 123-27 (see also Erratum ibid., p. 3420(1963).

Van der Merwe, J .H. Structure' of epitaxial crystal interfaces. Surface Science, 1972,31, 198-28.

Matthews, J. W .Defects associated with the accommodation of misfit between crystals. J. Vac. Sci. Technol., 1975, 12, 126-33.

Bean, l.C.; Feldman, L.C.; Fiory, A. T.; Nakahara S. & Robinson, I.K. GexSi./Si strained layer superlattice growth by molecular beam epitaxy. J. Vac. Sci. Technol., A, 1984, 2, 436-40.

Kasper, E. Growth and properties of Si/SiGe superlattices. Surface Science, 1986, 174, 630.39.

Van de Leur, R.; Schellingerhout, A.; Tuinstra, F. & Mooij, J. Critical thickness for pseudomorphic growth of Si/Ge alloys and superlattices. Appl. Phys., 1988, 64, 3043-50.

Chidambarrao, D.; Srinivasan, G.; Cunningham, B. & Murthy, C. Effecfs ofPeierls barrier and epithreading dislocation orientation on the critical thickness in heteroepit.axial structures. Appl. Phys. Lett.,f 1990, 57, 1001-3.

Lo, y .H. New approach to grow pseudomorphic structures over the critical thickness.t Appl. Phys. Lett., 1991,59, 2311-313.

Kasper, E. & Herzog, H.J. Elastic strain and misfit dislocation density in Si O.92 GeO.O8 Films on silicon substrates. Thin Solid Films, 1999, 44, 357- 70.

Bean , J.C.; Sheng, T.T.; feldman, L.C.; Fiory, A.T. & Lynch, R.T. .Pseudomorphic growth of GexSi1-x on silicon by molecular beam epitaxy . Appl. Phys. Lett., 1986, 48, 102-04

Meyerson, B.S. Low temperature silicon epitaxy by ultra high vacuum/chemical vapour deposition. Appl. Phys. Lett., 1986. 48. 797-99.

Meyerson, B.S.; Uram, K.J. " LeGoues, F. K. Cooperative phenomena in silicon/germanium low temperature epitaxy. Appl. Phys. .Lett., 1988, 53,2555-557.

Murota, J .; Nakamura, N .; Kato, M. & Mikoshiba, .N. Low temperature silicon selective deposition and epitaxy on silicon using the thermal decomposition of si lane under ultra clean

environment. Appl. Phys. Lett., 1989, 54 1007-9.

Racahelli', M. & preve, D. Low temperature selective epitaxy by ultrahigh vacuum chemical vapour deposition from SiH4 and GeH4. Appl. Phys. Lett., 1991r 58, 2096-98.

Greve, Do Wo & 'Racanelli, M. Construction and operation of an ultrahigfh vacuum chemical

vapour deposition epitaxiat,reactor for growth of GexSi,-x. .I: Vac. Sci. Technol. B, 1990, 8,

-15.

Green, M.L.; Brasen, D.; Temkin, H.; Yadvish, .R.D.; Boone, T.; Feldman; L.C.; Geva, M.

& Spear, B.E. High gain Si-.Ge heterojunction .bipolar transistors grown by rapid thermal chemical

vapour depo.sition. Thin Solid Films, 1990,184, 107-11.

Green, M.L.; W~ir, B.E.; Brasen, D.; Hsieh, W. F.; Higashi, q.; Feygens~n, A.; Feldman,

L.C. & Headrick, R.L. Mechanically and thermally stable Si-Ge films and heterojunction bipolar

transistors grown by rapid thermal chemical vapor d~position at 900 °C. J. Appl. Phys.,1991, 69, 745-51.

Garone, P .; Sturm, J.C.; Schartz, p .V .; Schwartz, S.A. & Wilkens, B.J. Silicqn f vapor phase

epitaxial growth cqtalysis by the presence of germane. 'Appl. Phys. Lett., 1990, 56, 1275-277.

Hoyt, J.; King, C.A.; Noble, D.B.; Gronet, C.M.; Gibbons, J.F .; Scott, M.P .; Laderman,

S.S.; Rosner, S.J; Nauka, K.; Turner, J. & Kamins, T .I. Limited reaction proccssing: Growth

of S;I-xGex/ Si fot heterojunction bipolar transistor applications. Thin Solid Films, 1990, 184, 93-106.

Dutartl1e, D.; Warren, P.; Berbezier, I. & Perret, P. Low temperature silicon and

Si -xGex epitaxy by fapitl thermal chemical vapour deposition using hydrides. Thin Solid

Films, 992, 222, 52-56.

Sedgwick, T .O.; ;Berbezier)it, M. & Kuan, T .S. I Low temperature selective epitaxial growth of

silicon at atmospheric pressure. Appl. Phys. Lett., 1989, 54, 2689-691.

Hsu, T.; Anthony, B.; Qian, R.; Irby,J.; Kinosky, D.; I Mahajan, A.; Banerjee, S.;

Magee~ C. & Tasch, A. Advances in remote plasma-enhanced chemical vapour deposition

for low temperature in situ hydrogen plasma clean and Si and Si,1-xGex Epitaxy. J. Electron.

Mater.; 1992,.21, 65- 74.

.

Posthill, J.B.; Rudder, R.A.; Hattangady, S.V.; Fountain, G.G. & ~arku~as, R.J. On the feasibility

of growing dilulte CxSi1-x epitaxial alloys. Appl.Phys. Lett. , 1990, 56734-36.

Iyer, S.S.; Eberll K.; Goorsky, M.S.; LeGoues, F .K. & Tsang, J.C. Syntpesis of Si1-y Cy alloys

by molecular beam epitaxy. Appl. Physj Lett.,1992, 60, 365-58.

Iyer, S.S.; Eberl, K.; Powell, A.R. & Ek, B.R. Si 1-x-y Ge C y ternary alloys-extending Si-based

heterostructures. Microelectronic Engineering.,992,19, 351-56. ,

Eberl, K.; .Iyer, S. S.;Tsang, J.C.; Goorsky,s. s. & LeGoues, F .K. The growth and

characterization of Si1-yCy allow on Si(001) substrareI . J: Vac. Sci. Technol., B, 1992,10,

-36.

Gporsky, M. S.; Eberl. s.LeGoues, F.; Angilelto, J. & Cardone, F,Thermal stability

of Si1-xCx/Si strained iayer superlattices. Appl. Phys.Lett ., 1992, 60, 2758-760.

Eberl, K.; Iyer, S.S. & LeGoues, F.K. Strain symmetrisation effects in pseudomorphic

Si l-y Cy /Si . Ge su perlattices. .Appl. Phys. Lett., 1994,64, 739-41.

Faschinger, W.; Zerlauth, S.; Bauer, G. & Palmetshofer, L. Electrical properties of Si1-x Cx alloys and modulation-doped Si/Si1-x Gex/ Si structures. App/. Phys. Lett., 1995, 67,3933-935.

Mi, J.; Letourneau, p .; Ganiere, J.D.; Ganiere, J.D.; Gailhanou M.; Dutoit, M.; Dubois, c. & Dupuy, J. C.

Silicon-carbon random alloy epitaxy on silicon by rapid thermal chemical vapour deposition.

Mater. Res. Soc. Symp. Proc., 1994, 342,255-59.

Ray, S. K.; McNeill, D. W .; Gay, D. L.; Maiti, C. K.; Armstrong, G. A.; Armstrong, B.

M. & Gamble, H. S. Comparison of Si1-Y CY films produced by solid-phase epitaxy and rapid

thermal chemical vapor deposition. Thin Solid Films, 1997, 294, 149-52.

Strane, J. W.; Stein, H.J.; Lee, S.R.; Picraux, S. T.; Watanabe, J. K. & Mayer, J. W. Precipitation

and relaxation in strained Si 1-y C y/Si hetero structures. J. Appl. Phys., 1994, 76, 3656-668.

Osten, H.J .; Bugiel, E. & Zaumseil, P. Antimony-mediated growth of epitaxial Ge1-yCy layers

on Si(001 ). J: Cryst. Growth, 1994, 142, 322-26.

Osten H.J. & Klatt, J. In situ monitoring of strain relaxation during antimony-mediated growth

of Ge and Ge1-y Cy layers on Si(001) using reflection high energy electron diffraction. Appl.Phys. Lett., 1994,65, 630-32.

Kolodzey, J.; O'Neil, P.A.; Zhang, S.; Orner, B.A.; Roe, K.; Unruh, K.M.; Swann, C.P .; White, M.M. & Shah, A.I.Growth of germaniumcarbon alloys on silicon substrates by molecular beam epitaxy. Appl. Phys. Lett., 1995,67, 1865-867.

Chen,F.; Troger, R.T.; Roe, K.; Dashell, M.D.; Jonczyk, R.; Holmes, D.S.; Wilson,R.J.& Kolodzey, J. Electrical properties of Si 1-x-y Gex Cy and Ge1-y Cy J. Electron .Mater., 1997, 26,1371-375.

Published
2013-01-01
How to Cite
Maiti, C., Bera, L., Maikap, S., Ray, S., Chakrabarti, N., Kesavan, R., & Kumar, V. (2013). Growth of Silicon- Germanium Alloy Layers. Defence Science Journal, 50(3), 299-315. https://doi.org/10.14429/dsj.50.3719
Section
Electronics & Communication Systems