Stereospecific Synthesis of trans-t-Butyl Beta-Methyl-Beta-(p-Bromophenyl)-Glycidate and its Pyrolysis
Keywords: Darzens condensation, Chloroperbenzoic acid
Abstracttrans-t-Butyl Beta-(p-bromophenyl)-glcidate has been synthesised by the stereospecific epoxidation of the unsaturated ester (V)using m-chloroperbenzoic acid. The trans-configuration was assigned on the basis of spectral analysis and comparison with the similar product obtained in the Darzens condensation. The ester on pyrolysis yields a-methyl a- (p-bromophenyl) acetaldehyde.
How to Cite
Bansal, R., & Sethi, K. (2014). Stereospecific Synthesis of trans-t-Butyl Beta-Methyl-Beta-(p-Bromophenyl)-Glycidate and its Pyrolysis. Defence Science Journal, 29(4), 151-152. https://doi.org/10.14429/dsj.29.6507
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