Polarographic Study of Cd-Schiff Base Complex

  • M. S. Patel Saurashtra University, Bhavnagar
  • T. Trivedi Saurashtra University, Bhavnagar
  • D. N. Vyas Saurashtra University, Bhavnagar
DOI: https://doi.org/10.14429/dsj.29.6457
Keywords: Polarographic behaviour, DMF water media, Dielectric constant

Abstract

Polarographic behaviour of Cd/sup 2/+ with a schiff base salicyladehyde trisbuffer has been studied in DMF water media of three different compositions (viz., 0%, 30% and 50% v/v of DMF). Stability constant, free energy change delta G, enthalpy change delta H and entropy change delta S of the systems are calculated for all the three media at three different temperatures (viz., 30 degree centigrade, 40 degree centigrade and 50 degree centigrade). A relation of halfwave potential of the system with the dielectric constant of the medium has also been verified.

Author Biographies

M. S. Patel, Saurashtra University, Bhavnagar
Department of Chemistry, Saurashtra University, Bhavnagar
T. Trivedi, Saurashtra University, Bhavnagar
Department of Chemistry, Saurashtra University, Bhavnagar
D. N. Vyas, Saurashtra University, Bhavnagar
Department of Chemistry, Saurashtra University, Bhavnagar
Published
2014-02-24
How to Cite
Patel, M., Trivedi, T., & Vyas, D. (2014). Polarographic Study of Cd-Schiff Base Complex. Defence Science Journal, 29(1), 7-10. https://doi.org/10.14429/dsj.29.6457
Issue
Vol 29 No 1
Section
General Papers
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