Polynuclear Complexes of Fumaric Acid Dihydrazide with Cu (II), Ni (II) and Co (II)

Authors

  • C. G. Kumbhar Institute of Armament Technology, Pune

DOI:

https://doi.org/10.14429/dsj.36.5961

Keywords:

Fumaric acid dihydrazide, TGA, DTA

Abstract

Metal chloride and metal sulphate complexes of fumaric acid dihydrazide (FZ) of the type MX2.FZ.H2O, [M = Cu (II), Ni (II), and X = Cl2 and 1/2 SO4] and NiX2.FZ.2H2O have been prepared. Coordination occurs though oxygen of the> C = O and nitrogen of the -NH2 of the hydrazide group. A polymeric octahedral structure for MCI2 complexes and sulphate bridged quadricoordinate structure for MS04 complexes has been proposed. TGA and DTA results are also reported.

Author Biography

C. G. Kumbhar, Institute of Armament Technology, Pune

Institute of Armament Technology, Pune-41 1025

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Published

2014-01-20

How to Cite

Kumbhar, C. G. (2014). Polynuclear Complexes of Fumaric Acid Dihydrazide with Cu (II), Ni (II) and Co (II). Defence Science Journal, 36(1), 57–62. https://doi.org/10.14429/dsj.36.5961

Issue

Vol. 36 No. 1

Section

General Papers

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