Structure Thermolysis Relationships for Energetic Materials

  • Thomas B. Brill Department of Chemistry, University of Delaware Newark,USA
DOI: https://doi.org/10.14429/dsj.41.4416
Keywords: Fast thermolysis, Condensed phase, Gas phase reactions

Abstract

The technique of fast thermolysis/FTIR spectroscopy, in which temperature profiling of the condensed phase is also conducted, is described. Applications are given to show how the formation of NO2, HONO, NO, and CH2O can be related to underlying parent molecular features. The effect of pressure in the 1-1000 psi range on the overall process is presented along with an example of how pressure can be used to distinguish the gas phase reactions from the condensed phase reactions during fast thermolysis.

Author Biography

Thomas B. Brill, Department of Chemistry, University of Delaware Newark,USA
Department of Chemistry, University of Delaware Newark,USA
Published
2013-01-01
How to Cite
Brill, T. (2013). Structure Thermolysis Relationships for Energetic Materials. Defence Science Journal, 41(2), 111-129. https://doi.org/10.14429/dsj.41.4416
Issue
Vol 41 No 2
Section
Chemical Science & Technology
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