Low-cost Adsorbents for the Removal of Mercury (11) from Aqueous Solution-A Comparative Study

Abstract

The establishments of the Ministry of Defence, specifically ordnance factories and public sector undertakings (like Bharat Electronics Ltd), carry out operations like electroplating, metal1
surface finishing, solid-state wafer processing, and initiatory manufacturing (lead azide, mercury fulminate), which generate waste water contaminated with hazardous heavy metals. Mercury
and its compounds are known to be highly toxic, both for the living organisms and theenvironment. To protect public health, a regulatory discharge standard of mercury, as low as 0.01 mgll, has been imposed and is expected to be even stricter in the future. A promising method for effective mercury discharge control is to employ suitable adsorbents for the removal of mercury from the contaminated aqueous stream.
This paper describes the effectiveness of low cost and locally available, untreated and chemically-treated adsorbents for the removal of mercury from the aqueous solution. Their effectiveness has been compared with that of chemically-treated granular activated carbon. Treated sawdust and untreated weathered coal were found to be the most suitable low-cost adsorbents in addition to treated granular activated carbon for the removal of mercury from aqueous solution. Under the optimised conditions, ie, adsorbent dose 10 gll, pH 6, contact time 48 h, and initial concentration of mercury 3 mgll, the removal of mercury was found to be 99.8 per cent, 99.8 per cent, and 99.7per cent, using treated granular activated carbon, treated sawhust, and untreated weathered coal, respectively.
The adsorption parameters were determined using both Langmuir and Freundlich isotherm models. Surface complexation and ion exchange were the major removal mechanisms involved.
The adsorption isotherm studies clearly indicated that the Langmuir model is in good agreement, with the experimental data on the adsorptive behaviour of mercury on treated granular activated carbon, whereas, the experimental data on adsorptive behaviour of mercury on weathered coal and treated sawdust follow both Langmuir and Freundlich isotherm models. The paper presents the results of the experimental studies as well as the model parameters.