Study of an Energetic-oxidant Co-crystal: Preparation, Characterisation, and Crystallisation Mechanism

Authors

  • Han Gao Nanjing University of Science and Technology, School of Chemical Engineering
  • Wei Jiang Nanjing University of Science and Technology, School of Chemical Engineering
  • Jie Liu Nanjing University of Science and Technology, School of Chemical Engineering
  • Gazi Hao Nanjing University of Science and Technology, School of Chemical Engineering
  • Lei Xiao Nanjing University of Science and Technology, School of Chemical Engineering
  • Xiang Ke Nanjing University of Science and Technology, School of Chemical Engineering
  • Teng Chen Nanjing University of Science and Technology, School of Chemical Engineering

DOI:

https://doi.org/10.14429/dsj.67.10188

Keywords:

Energetic co-crystal, Ammonium perchlorate, CL-20, Solvent evaporation method, Intermolecular hydrogen bond

Abstract

An energetic co-crystal consisting of the most promising military explosive 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20) and the most well-known oxidant applied in propellants ammonium perchlorate has been prepared with a simple solvent evaporation method. Scanning electron microscopy revealed that the morphology of co-crystal differs greatly from each component. The X-ray diffraction spectrum, FTIR, Raman spectra, and differential scanning calorimetry characterisation further prove the formation of the co-crystal. The result of determination of hygroscopic rate indicated the hygroscopicity was effectively reduced. At last, the crystallisation mechanism has been discussed.

Author Biographies

Han Gao, Nanjing University of Science and Technology, School of Chemical Engineering

Dr Han Gao, major in energetic co-crystal materials.

Wei Jiang, Nanjing University of Science and Technology, School of Chemical Engineering

Prof. Wei Jiang, major in energetic materials.

Jie Liu, Nanjing University of Science and Technology, School of Chemical Engineering

Dr Jie Liu, major in nano explosives.

Gazi Hao, Nanjing University of Science and Technology, School of Chemical Engineering

Dr Gazi Hao, major in nano energeic catalysts.

Lei Xiao, Nanjing University of Science and Technology, School of Chemical Engineering

Dr Lei xiao, major in nano explosives used in PBX.

Xiang Ke, Nanjing University of Science and Technology, School of Chemical Engineering

Dr Xiang Ke, major in nano thermite.

Teng Chen, Nanjing University of Science and Technology, School of Chemical Engineering

Dr Teng Chen, major in nano energetic composites.

Downloads

Published

2017-09-19

How to Cite

Gao, H., Jiang, W., Liu, J., Hao, G., Xiao, L., Ke, X., & Chen, T. (2017). Study of an Energetic-oxidant Co-crystal: Preparation, Characterisation, and Crystallisation Mechanism. Defence Science Journal, 67(5), 510–517. https://doi.org/10.14429/dsj.67.10188

Issue

Vol. 67 No. 5

Section

Armaments & Explosives

License

 Where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India